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WATER CHEMISTRY PROBLEMS
The proper
maintenance of the water chemistry will go a long way to avoid problems. Once
the chemistry has been optimized, the chemistry will vary depending upon the
nature of the chemicals being added on a regular basis. Daily water testing is
important as changes can occur quickly and should be corrected to avoid
potentially undesirable water conditions.
WATER
CHEMISTRY PROBLEMS: pH & Alkalinity
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|
PROBLEM |
POSSIBLE
CAUSES |
ALAN’S
SOLUTIONS |
|
Recurring high pH (above 7.8) |
·
Low total alkalinity (below 80 ppm) makes it difficult to
control pH
·
Low calcium hardness (below 200 ppm)
·
Frequent additions of high pH chlorine products as: calcium,
lithium or sodium hypochlorite
·
Failure to test pH frequently and adjust, as needed
·
Addition of too much pH Plus (sodium carbonate) |
Test the water for total alkalinity and, if less than
80 ppm, adjust by adding SUN Alkalinity Plus as directed.
Test the water for calcium hardness and adjust as
necessary using SUN Hardness Treatment.
Because the pH can be affected by several factors, test
the pH frequently and add the appropriate pH control chemicals – SUN Plus
or Minus – as required to keep the pH within the optimum range of
7.2-7.8. |
|
Recurring low pH (below 7.2) |
·
Low total alkalinity (below 80 ppm) makes it difficult to
control pH
·
Use of low pH products as: trichlor chlorine or bromine
tablets
·
Addition of too much pH Minus or muriatic acid
·
Failure to test pH frequently and adjust, as needed
·
Natural effects of bathers in water, acid rain and atmospheric
carbon dioxide |
Test the water for total alkalinity and, if less than
80 ppm, adjust by adding SUN Alkalinity Plus as directed. The use of
trichlor or bromine tablets will require regular additions of SUN Plus
to offset their acidic nature. Test the pH frequently and add the
appropriate pH control chemicals – SUN Plus or Minus – as required to
keep the pH within the optimum range of 7.2-7.8 |
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pH bounce (fluctuates frequently) |
·
Total alkalinity is too low (below 80 ppm) to buffer the pH
·
Addition of too much pH control chemical |
Adjust the total alkalinity to 80-150 ppm by adding the
appropriate amount of SUN Alkalinity Plus. |
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High Total Alkalinity (TA) (above 150 ppm) |
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Low Total Alkalinity (TA) (below 80 ppm) |
·
Failure to regularly test and adjust the pH and Total
Alkalinity, as needed. |
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Hints/Preventive Maintenance: |
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WATER
CHEMISTRY PROBLEMS: Calcium Hardness
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|
PROBLEM |
POSSIBLE
CAUSES |
ALAN’S
SOLUTIONS |
|
High calcium hardness (above 400 ppm) |
·
Addition of too much calcium hardness increaser |
High levels of calcium hardness can lead to cloudy
water and scale formation, especially in the presence of high pH and total
alkalinity. Levels up to 400 ppm are usually not a problem, if normal
chemistry is maintained. Levels over 400 ppm can be controlled by the
addition of SUN Stain & Scale Inhibitor or the replacement of some of
the water with softer water. To prevent further increases in the calcium
hardness levels, do not use products containing calcium hypochlorite for
sanitizing or shocking purposes. |
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Low calcium hardness (below 200 ppm) |
·
Failure to add calcium hardness increaser |
Low levels of calcium hardness can lead to the
corrosion of masonry surfaces, especially in the presence of low pH and
total alkalinity. Masonry pools should be increased to 200 ppm and vinyl
and fiberglass pools raised to 80-200 ppm. SUN Hardness Treatment
can be used to boost the calcium hardness to the proper level. |
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Hints/Preventive Maintenance: |
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WATER
CHEMISTRY PROBLEMS: TDS
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High total dissolved solids (TDS) (above 3000 ppm) |
·
Long term buildup due to chemical additions – every chemical
added to pool water contributes to TDS |
Replace some of the water with fresh water that is low
in TDS. If there are no signs of a clarity problem, TDS is usually not a
problem. Replacement of water lost due to pump out, backwashing and splash
out will help keep the TDS in check. If there is a persistent water quality
problem that defies explanation, TDS should be looked into as a possible
contributing factor by bringing a water sample to your professional SUN
dealer. |
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Hints/Preventive Maintenance: |
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WATER
CHEMISTRY PROBLEMS: Sanitizers
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High rate of chlorine usage |
·
High pH (above 7.8)
·
Lack of adequate level of chlorine stabilizer
·
Extreme heat
·
Introduction of large amounts of debris & waste
a)
High bather usage
b)
Children urinating in the pool
c)
Heavy rains
·
High combined chlorine level
·
Presence of algae
|
Make sure to maintain proper levels of Free Chlorine,
pH and stabilizer. If needed, adjust pH with SUN Plus or Minus
and stabilizer with SUN Conditioner; filter continuously. Inspect
for the presence of algae or bacterial slimes. If present, see Algae
Problems. Make sure that children are not urinating in the pool, vacuum all
debris from the bottom, and clean the skimmer.
The addition of a SUN algaecide can be useful in
lowering the amount of chlorine required to maintain proper water
conditions, especially during hot weather and periods of high bather use.
Combined chlorine (chloramines) is ineffective as a
pool water sanitizer. Shock the pool with SUN-Brite non-chlorine
shock, which converts the ineffective Combined Chlorine into Free Chlorine.
Add enough shock until the difference between the Combined Chlorine and Free
Chlorine is within 1 ppm. If needed, add SUN Booster or SUN-Burn
to raise the Free Chlorine level to 1-3 ppm. |
WATER CHEMISTRY PROBLEMS: Sanitizers
(continued)
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PROBLEM |
POSSIBLE
CAUSES |
ALAN’S
SOLUTIONS |
|
High Free Chlorine levels |
·
Adding too much chlorine (incorrect feeder setting)
·
Shocking too frequently or using too much shock
·
Low bather demand |
The Free Chlorine level will lower over time as the
chlorine is used up. Thereafter, adjust the chlorine being added to the
pool based on how the pool is being used and the water temperature. Add
more during times of heat and peak usage, and less during cooler and less
active periods of usage. If chlorine is added at too high a rate, the level
of Free Chlorine can build up. Always follow label directions carefully. |
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Low Free Chlorine levels |
·
High bather usage, heavy rains or extreme heat
·
Lack of adequate level of chlorine stabilizer
·
High pH (above 7.8)
·
Poor circulation or short filter cycle
·
Presence of algae and organic waste products |
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High combined chlorine (chloramines – causes chlorine
odors) |
·
Presence of organic waste products (children urinating in the
pool)
·
Insufficient shock treatment
·
Failure to adequately maintain Free Chlorine
·
Poor circulation and filtration
·
Presence of algae and bacterial slimes |
Combined chlorine (chloramines) can be odorous and
irritating and is ineffective as a pool water sanitizer. Shock the pool
with SUN-Brite non-chlorine shock, which converts the ineffective
Combined Chlorine into Free Chlorine. Add enough shock until the difference
between the Combined Chlorine and Free Chlorine is within 1 ppm. If needed,
add SUN Booster or SUN-Burn to raise the Free Chlorine level
to 1-3 ppm. |
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Chlorine/Sanitizer Appears Ineffective |
·
Presence of organic waste products (children urinating in
pool) or lawn fertilizer
·
High levels of combined chlorine (chloramines)
·
Insufficient shock treatment
·
Presence of algae and bacterial slimes
·
Failure to adequately maintain Free Chlorine
·
Poor circulation and filtration
·
High pH and/or stabilizer level and/or TDS |
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Hints/Preventive Maintenance: |
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WATER CHEMISTRY PROBLEMS: Sanitizers
(continued)
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PROBLEM |
POSSIBLE
CAUSES |
ALAN’S
SOLUTIONS |
|
High rate of bromine usage |
·
Very high pH (above 8.0)
·
Introduction of large amounts of debris & waste
a)
High bather usage
b)
Children urinating in the pool
c)
Heavy rains
·
High water temperatures
·
Presence of algae and bacterial slimes |
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High bromine levels |
·
Adding too much bromine (incorrect feeder setting)
·
Shocking too frequently or using too much shock
·
Low bather demand |
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Low bromine levels |
·
Insufficient dosage of bromine (lack of proper brominating
feeder)
·
Presence of algae and bacterial slimes
·
High bather usage, heavy rains or extreme heat
·
Very high pH (above 8.0)
·
Poor circulation or short filter cycle |
Shock the pool with a quick-dissolving product such
as: SUN-Brite, SUN Booster or SUN-Burn. Repeat shock
treatment until a bromine level of at least 5 ppm can be maintained
overnight. Check pH and adjust as needed with SUN Plus or Minus;
filter continuously. Resume normal bromination and filtration. Keep
brominator filled with tablets for best results. |
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Hints/Preventive Maintenance: |
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WATER CHEMISTRY PROBLEMS: Shock
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Not responding to shock treatment |
·
Failure to add enough shock to effectively deal with the
problem
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Hints/Preventive Maintenance: |
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WATER CHEMISTRY PROBLEMS:
Chlorine Stabilizer
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PROBLEM |
POSSIBLE
CAUSES |
ALAN’S
SOLUTIONS |
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·
Long-term use of stabilized chlorine products (including shock
products)
·
Excessive additions of cyanuric acid stabilizer |
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Low stabilizer levels |
·
Insufficient dosage of cyanuric acid
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Replacement of all or part of the water through draining or
backwashing |
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Hints/Preventive Maintenance: |
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PROPER RANGES FOR
POOL/SPA WATER
pH:
7.2 - 7.8 (ideal 7.2 -
7.6)
Total Alkalinity:
80 - 150 ppm
Free Chlorine: 1.0 - 3.0 ppm
Combined Chlorine: less
than 1.0 ppm above Free Chlorine
Bromine:
3 - 5 ppm
Calcium Hardness: 175
- 400 ppm
Cyanuric Acid (Stabilizer): 20 - 40
ppm in northern areas; 40 - 100 in sunbelt areas
Total Dissolved Solids:
maximum level 3,000 ppm
Iron:
0 ppm
Copper:
0 ppm |
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